Homogeneous catalysis
The latest chemistry news and research on homogeneous catalysis, including photocatalysis, asymmetric catalysis and organocatalysis, from the Royal Society of Chemistry's magazine, Chemistry World
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ResearchSimplified hydroformylation replaces rhodium with base metal
Bench-friendly asymmetric hydroformylation swaps toxic gas and expensive catalyst for cheap reagents and mild conditions
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ResearchClassic cross-coupling reactions rerouted to make new products
Combination of Suzuki–Miyaura and Buchwald–Hartwig couplings produces carbon–nitrogen–carbon linked compounds
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ResearchLong-lived excited states open the door to earth-abundant metal photocatalysts
New findings show that cobalt (III) complexes can catalyse reactions not previously thought possible
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ResearchSmall ring insertion expands structural editing toolbox
Bicyclic ring system made by adding a bicyclobutane into a thiophene
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OpinionBoosting cubane synthesis with photosensitizers
Leaping to a greener approach for cubane synthesis
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Research’Photoredox catalysis goes asymmetric’: counterion strategy a breakthrough in reaction control
Ion-pairing enables chemists to reach previously inaccessible enantiomers
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ResearchHomogeneous catalysis boosted by electrochemical recovery of precious metal complexes
Process can recover metals from industrially important catalysts
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ResearchChirality-flipping reaction could completely change total synthesis strategies
Photocatalytic reaction that inverts configuration of chiral carbon centres offers new stereochemical editing logic
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OpinionDavid MacMillan: ‘The medal is the real celebrity’
The Nobel prize-winner on the joys of handing out his medal to everyone, chatting with William Shatner and Alex Ferguson, and the pain of being a Scottish football fan
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ResearchMicrodroplets tackle scale-up issues for enzyme-photocoupled catalysis
Gas-spray reactor enhances light illumination efficiency and boosts rate of reaction
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FeatureHow organocatalysis won the Nobel prize
Jamie Durrani tells the story of how two young upstarts, Ben List and David MacMillan, created a whole new field of catalysis
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ResearchExplainer: why has asymmetric organocatalysis won the chemistry Nobel prize?
In a rather unexpected move by the Nobel committee, this year’s prize in chemistry has been awarded to Benjamin List and David MacMillan
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NewsAsymmetric organocatalysis scoops 2021 chemistry Nobel prize
Benjamin List and David MacMillan recognised for research that makes chemistry greener
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WebinarSublime precursors: how modelling organometallics at surfaces drives innovation in materials processing
Explore atomic-scale simulation workflows – and learn about key precursor properties and the thermodynamics of adsorption
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ResearchCounterintuitive catalyst gives purer products when used in less enantiopure form
Unusual example of ‘hyperpositive’ nonlinear effect is a first for asymmetric catalysis
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ResearchLight intensity changes can switch photocatalyst between one- and two-photon mechanisms
Simple optical lens behind strategy for manipulating photochemical reactivity
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ResearchNew chiral carbene expands ligand reservoir for asymmetric catalysis
Introducing rigidity boosts enantioselectivity
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OpinionChiral curiosities
The challenges posed by asymmetry go hand in hand with fascinating insights into developmental biology
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ResearchEnzyme helps photoredox get enantioselective
Enantioenriched amine synthesis is inaugural example of photoredox and enzyme collaboration
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ResearchTagging drugs with heavy hydrogen made as easy as flicking a light switch
Photoredox reaction simplifies metabolism studies by swapping hydrogen for deuterium or tritium