Inorganic chemistry – Page 9
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ResearchRare subvalent compound sits on the fence between semiconductors and intermetallics
Liquid indium solvent and sulfur-poor conditions allow scientists to create a new subchalcogenide
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ResearchUranium-reducing electrode cleans up groundwater
Electrochemical technique could limit spread of uranium at contaminated sites
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ResearchIntense sound fields make mercury react with water
After nearly a century, scientists can explain why a grey cloud forms when mercury and water are sonicated
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ResearchTrigold anion is first example of strange twisted aromaticity
A blue tin–gold cluster is the first to show in-plane σ-Möbius aromaticity
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ResearchDouble aromaticity found in boron analogue of metallabenzene
Boron–rhenium cluster is both σ- and π-aromatic
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ResearchFirst stable solid pentavalent plutonium compound stumbled upon by chance
Never-before-seen form of plutonium could shake up models of how radioactive contaminants disperse in the environment
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ResearchCopernicium behaves like a volatile noble liquid, simulations suggest
Relativity plays a part in making element 112 very different to its counterparts in group 12
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![An image showing a single-crystal X-ray derived model of [MH6] complex](jpg/501406_full_text__crimmin_161621_859886.jpg)
ResearchTransition metal complex with geometry predicted over 100 years ago raises eyebrows
A hexagonal planar complex containing rare palladium–magnesium bonds has been reported for the first time
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FeatureAtom-by-atom experiments at the edge of the periodic table
Only a few atoms of oganesson have ever been made – and they all vanished in less time than it took you to read this
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ResearchLarge gold nanoclusters are surprisingly stable paramagnets
An odd electron makes the magnetism
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ResearchHuman biases cause problems for machines trying to learn chemistry
Including ‘unpopular’ reagents and reaction conditions into datasets could lead to better machine-learning models
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ResearchSuperheavy oganesson is a semiconductor
The heaviest element known continues to defy the rules of the periodic table
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OpinionThe third degree on actinide covalency
The often ignored elements are attracting chemists’ attention again
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ResearchIonisation energy of promethium fills one of the last holes in periodic table
Experiment puts an end to 75-year-old mystery
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ResearchFirst isolable thorium nitride complex made
Researchers use new complex to probe covalency of actinide–ligand double bonds
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ResearchChiral borane complexes catalyse new synthesis opportunities
N-heterocyclic carbene-borane complexes with a rare stereogenic boron centre demonstrate potential in stereoselective catalysis
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ResearchFirst atom-thick perovskites show there’s no limits to crystallinity
Could 2D perovskite oxides become the next graphene?
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FeatureVictor Ninov and the element that never was
20 years on, Kit Chapman investigates how a scientific scandal unfolded
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ResearchBrown ring molecule defies the very definition of oxidation state
Classic nitrate test compound isolated for the first time challenges chemistry governing body’s ideas on oxidation state