Organic chemistry – Page 12
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Research
Study finds Goldilocks organoborane catalysts for fluorination
Tuning fluoride ion affinity opens a window for organoborane phase transfer catalysis in nucleophilic fluorination reactions
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Research
Robot chemist snaps 3D building blocks together like Lego to make complex molecules
Automated synthesiser uses a new class of boronates that are a thousand times more stable than those previously used
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Opinion
We need our simple symbols, but machines might not
Will the curly arrow still be with us in another 100 years?
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Research
Sulfonated macrocycle helps the medicine go down
A supramolecular approach makes alkaloid drugs taste less bitter
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Research
Atom-swapping reaction sequence turns cyclic diarylmethanes into diarylethers
Strategy that stitches three different reactions together could be useful for making pharmaceutical intermediates
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Opinion
A century of curly arrows
Celebrating the simple symbols that – along with their straight counterparts – encapsulate complex chemical behaviours
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Research
Curie temperature high makes organic ferroelectric pair stand out
Homochiral organic ferroelectrics get set to upgrade smart and medical devices
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Opinion
A transition metal handyman
Using nickel templating to promote a large molecule for organic electronics
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Research
Engineered enzyme speeds up sedate organic reaction
Biochemical optimisation applied to the Morita–Hillman–Baylis reaction
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Feature
Wiring up organic synthesis
James Mitchell Crow talks to the organic chemists using electrochemistry to add or remove electrons to their molecules at the flick of a switch
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Research
40-year-old mystery of why some molecules break all cyclisation rules has been solved
Molecules that blatantly violate Woodward–Hoffmann rules could lead to general theory of cyclisation in polar compounds
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News
Chemistry Nobel laureate Robert Grubbs dies at 79
US chemist shared 2005 prize for his role in developing the metathesis method in organic synthesis
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News
The curious incident of the catalytic amine that never was
A series of unfortunate events and a missed control experiment meant palladium sneaked its way into a supposedly amine-catalysed reaction
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Research
Diels-Alder reaction directly observed under the microscope
Simple ring-forming reaction followed on a surface for the first time using scanning probe microscopy
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Research
Doubly negative dianions can form π hole bonds too
Researchers report an attractive interaction between two doubly negative dianions for the first time
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Research
Record-breaking hexagon made out of fused aromatic rings
90 rings form the largest structure of its kind ever made
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Research
Dearomatisation, but without nasty reagents
New Birch reduction protocol creates solvated electrons without the dangerous combination of liquid ammonia and alkali metal