All palladium articles
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Research
Study questions sustainability benefits of replacing palladium with nickel in cross-coupling reactions
Common belief that Earth-abundant metals are green replacements for palladium may be misleading
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Research
Clever ligand design enables alcohol-directed C-H activation
Despite being the most common functional group in nature alcohols have proven difficult to functionalise
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Article
Next-generation ligands for complex coupling challenges
Improving phosphines for metal catalysis can deliver more efficient and sustainable syntheses
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Opinion
The power of oxygen
Running oxidations on lab scale and plant scale – with the help of bleach
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News
The curious incident of the catalytic amine that never was
A series of unfortunate events and a missed control experiment meant palladium sneaked its way into a supposedly amine-catalysed reaction
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Research
Unsupervised machine-learning tool could accelerate catalyst discovery
The approach was able to identify phosphine ligands that may form dinuclear palladium(I) complexes using only five experimental data points
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Research
Single atom catalysts double up to link oxidation and reduction
Photosynthesis inspires dual electrolytic system where iron-supporting shell envelops palladium-supporting ‘yolk’
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Research
Amine might end palladium’s reign over classic cross coupling reaction
Suzuki reaction now comes in an organocatalysed format
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Research
Palladium catalyst voyage prompts carbon–carbon bond formation rethink
Suzuki–Miyaura cross-coupling catalyst atoms leach away but then return to their supports
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Opinion
Exploring nickel reactivity in C–H activation chemistry
Coming closer to an alternative for palladium
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Research
First benzene-mimicking molecule made entirely from palladium
Palladium hexagon is a rare example of all-metal aromatic nanocluster
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Research
Transition metal complex with geometry predicted over 100 years ago raises eyebrows
A hexagonal planar complex containing rare palladium–magnesium bonds has been reported for the first time
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Research
Solo palladium in catalytic copper alloy reduces nitric oxide from vehicle exhausts
First system to work at low temperatures that doesn’t generate nitrous oxide
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Opinion
In search of ultimate selectivity
A catalyst that reacts only with aryl iodides, spurning bromides and chlorides
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Research
Crop rotation for catalysts
Chemists take a leaf out of agriculture books to devise method for extending catalyst lifetime
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Research
First four-twist aromatic molecule made
A di-palladium complex with 54 π electrons is the first quadruply twisted aromatic molecule
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Research
1500 reactions per day go with the flow
Automated flow chemistry system puts high-speed spin on drug discovery
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Research
First pentagonal 2D material unveiled
Palladium diselenide shows promise in electronics and photonics
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Research
Catalyst made from plant roots promotes Suzuki reaction
Ecocatalyst recycling strategy could be used to recover precious metal pollutants from contaminated sites
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Research
Liquid metal catalyst shows promise in industrial reaction
Palladium dispersed in gallium outperforms solid catalysts at high temperature